php build cron survey_emails_sender php PHP Warning Module curl alread

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php build/cron/survey_emails_sender.php
PHP Warning: Module 'curl' already loaded in Unknown on line 0
05:47:47 PM Start sending:
15 emails to send in next 50 seconds
05:47:47 PM Sending email to: jhmanchester@paychex.comawhite@paychex.com surv. created at: 2015-04-22 17:47:03
05:47:53 PM Mark as bad email the responder with id: 87
2015-04-22T17:47:53+03:00 ERR (3): exception 'Zend_Mail_Protocol_Exception' with message 'Too many @
' in /home/max/projects/tmf/library/Zend/Mail/Protocol/Abstract.php:431
Stack trace:
#0 /home/max/projects/tmf/library/Zend/Mail/Protocol/Smtp.php(289): Zend_Mail_Protocol_Abstract->_expect(Array, 300)
#1 /home/max/projects/tmf/library/Zend/Mail/Transport/Smtp.php(211): Zend_Mail_Protocol_Smtp->rcpt('jhmanchester@pa...')
#2 /home/max/projects/tmf/library/Zend/Mail/Transport/Abstract.php(348): Zend_Mail_Transport_Smtp->_sendMail()
#3 /home/max/projects/tmf/library/Zend/Mail.php(1194): Zend_Mail_Transport_Abstract->send(Object(Zend_Mail))
#4 /home/max/projects/tmf/application/models/Email.php(26): Zend_Mail->send()
#5 /home/max/projects/tmf/application/models/Email.php(91): Email->sendEmail(Object(Zend_Mail))
#6 /home/max/projects/tmf/build/cron/survey_emails_sender.php(58): Email->sendSurveyRequestEmail(Array, 4)
#7 /home/max/projects/tmf/build/cron/survey_emails_sender.php(176): sendSurveyEmails()
#8 {main}
2015/04/22 05:47:53 Error occured when sending: jhmanchester@paychex.comawhite@paychex.com with error message: Too many @
05:47:53 PM Sending email to: semplic.k43e@gmail.com surv. created at: 2015-04-22 17:47:03
Set email: semplic.k43e@gmail.com with id in table responders_to_survey: 2519 as sent
Current time to start time difference: 7 sec
05:47:54 PM Sending email to: semplic.k43e+1@gmail.com surv. created at: 2015-04-22 17:47:03
Set email: semplic.k43e+1@gmail.com with id in table responders_to_survey: 2520 as sent
Current time to start time difference: 9 sec
05:47:56 PM Sending email to: semplic.k43e+2@gmail.com surv. created at: 2015-04-22 17:47:03
Set email: semplic.k43e+2@gmail.com with id in table responders_to_survey: 2521 as sent
Current time to start time difference: 10 sec
05:47:57 PM Sending email to: semplic.k43e+3@gmail.com surv. created at: 2015-04-22 17:47:03
Set email: semplic.k43e+3@gmail.com with id in table responders_to_survey: 2522 as sent
Current time to start time difference: 11 sec
05:47:58 PM Sending email to: semplic.k43e+3@gmail.com surv. created at: 2015-04-22 17:47:19
Set email: semplic.k43e+3@gmail.com with id in table responders_to_survey: 2527 as sent
Current time to start time difference: 13 sec
05:48:00 PM Sending email to: semplic.k43e+2@gmail.com surv. created at: 2015-04-22 17:47:19
Set email: semplic.k43e+2@gmail.com with id in table responders_to_survey: 2526 as sent
Current time to start time difference: 14 sec
05:48:01 PM Sending email to: semplic.k43e+1@gmail.com surv. created at: 2015-04-22 17:47:19
Set email: semplic.k43e+1@gmail.com with id in table responders_to_survey: 2525 as sent
Current time to start time difference: 15 sec
05:48:02 PM Sending email to: semplic.k43e@gmail.com surv. created at: 2015-04-22 17:47:19
Set email: semplic.k43e@gmail.com with id in table responders_to_survey: 2524 as sent
Current time to start time difference: 16 sec
05:48:03 PM Sending email to: semplic.k43e@gmail.com surv. created at: 2015-04-22 17:47:37
Set email: semplic.k43e@gmail.com with id in table responders_to_survey: 2529 as sent
Current time to start time difference: 18 sec
05:48:05 PM Sending email to: semplic.k43e+1@gmail.com surv. created at: 2015-04-22 17:47:37
Set email: semplic.k43e+1@gmail.com with id in table responders_to_survey: 2530 as sent
Current time to start time difference: 24 sec
05:48:11 PM Sending email to: semplic.k43e+2@gmail.com surv. created at: 2015-04-22 17:47:37
Set email: semplic.k43e+2@gmail.com with id in table responders_to_survey: 2531 as sent
Current time to start time difference: 26 sec
05:48:13 PM Sending email to: semplic.k43e+3@gmail.com surv. created at: 2015-04-22 17:47:37
Set email: semplic.k43e+3@gmail.com with id in table responders_to_survey: 2532 as sent
Current time to start time difference: 27 sec
05:48:14 PM Finished sending 12 emails
Fetching for surveys having unnoticed response ...
5 surveys found. Sending emails to creators ...
0 emails sent
max@max-X550LA:~/projects/tmf$