case dG -193300 94 8849199 sred break case Al dG -277700 120 43 sred b

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case "V":
$dG=-193300+94.8849199*$sred;
break;
case "Al":
$dG=-277700+120.43*$sred;
break;
case "Ti":
$dG=-275484.5+99.9020103*$sred;
$_parvz1=array(
"a"=>array("Al"=>-790,"B"=>772.6,"C"=>744.2,"Cr"=>-164.52,"Mn"=>-128.1,"Mo"=>-11.22,"Nb"=>-338.4,"Ni"=>14.63,"P"=>31.9,"S"=>3934,"Si"=>45.8,"Ta"=>-190.5,"Ti"=>-3137.6,"V"=>-1220,"Zr"=>0,"W"=>-116.3,"Cu"=>0,"As"=>0,"N"=>0),
"b"=>array("Al"=>0.393,"B"=>-0.32,"C"=>-0.256,"Cr"=>0.038,"Mn"=>0.044,"Mo"=>-0.0019,"Nb"=>0.1105,"Ni"=>0.00066,"P"=>0.016,"S"=>-2.09,"Si"=>0.018,"Ta"=>0.069,"Ti"=>0.894,"V"=>0.544,"Zr"=>0,"W"=>0.053,"Cu"=>0,"As"=>0,"N"=>0),
"c"=>array("Al"=>217.1,"B"=>149.5,"C"=>-151.8,"Cr"=>1.74,"Mn"=>-0.32,"Mo"=>-1.9,"Nb"=>24.3,"Ni"=>-0.066,"P"=>5.6,"S"=>-7725,"Si"=>2.3,"Ta"=>2.88,"Ti"=>-18414,"V"=>30,"Zr"=>0,"W"=>11.3,"Cu"=>0,"As"=>0,"N"=>0),
"d"=>array("Al"=>-0.123,"B"=>-0.077,"C"=>0.0755,"Cr"=>-0.00053,"Mn"=>0.00034,"Mo"=>0.00076,"Nb"=>-0.012,"Ni"=>0.000144,"P"=>0.00057,"S"=>4.17,"Si"=>0.00025,"Ta"=>-0.0015,"Ti"=>9.92,"V"=>-0.014,"Zr"=>0,"W"=>-0.005,"Cu"=>0,"As"=>0,"N"=>0),
);
$_parvz2=array(
"N"=>array("Al"=>-0.028,"C"=>0.13,"Cr"=>-0.047,"Mn"=>-0.02,"Mo"=>-0.011,"Nb"=>-0.06,"Ni"=>0.01,"Si"=>0.047,"Ti"=>-0.53,"V"=>-0.093,"W"=>-0.0015,"Zr"=>-0.63,"N"=>0,"S"=>0,"P"=>0,"Cu"=>0,"As"=>0),
"Zr"=>array("Al"=>0,"C"=>-0.603,"Cr"=>0.024,"Mn"=>0,"Mo"=>0.015,"Nb"=>0,"Ni"=>-0.018,"Si"=>0,"Ti"=>0.013,"V"=>0.0244,"W"=>0.01,"Zr"=>0.013,"N"=>-4.1,"S"=>0,"P"=>0,"Cu"=>0,"As"=>0),
"Ti"=>array("Al"=>0,"C"=>-0.603,"Cr"=>0.024,"Mn"=>0,"Mo"=>0.015,"Nb"=>0,"Ni"=>-0.018,"Si"=>0,"Ti"=>0.013,"V"=>0.0244,"W"=>0.01,"Zr"=>0.013,"N"=>-1.8,"S"=>0,"P"=>0,"Cu"=>0,"As"=>0),
"Al"=>array("Al"=>0.045,"C"=>0.091,"Cr"=>0.023,"Mn"=>0,"Mo"=>0.0144,"Nb"=>0,"Ni"=>-0.024,"Si"=>0.0056,"Ti"=>0,"V"=>0.06,"W"=>0.0096,"Zr"=>0,"N"=>-0.058,"S"=>0,"P"=>0,"Cu"=>0,"As"=>0),
"V"=>array("Al"=>0.18,"C"=>-0.34,"Cr"=>0.0147,"Mn"=>0,"Mo"=>0.01,"Nb"=>0,"Ni"=>0,"Si"=>0.042,"Ti"=>0,"V"=>0.015,"W"=>0.0077,"Zr"=>0,"N"=>-0.35,"S"=>0,"P"=>0,"Cu"=>0,"As"=>0),
);